Utente:Grasso Luigi/sanbox1/Esterificazione: differenze tra le versioni

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Grasso Luigi (discussione | contributi)
Riga 38:
: RCO<sub>2</sub>R′ + CH<sub>3</sub>OH → RCO<sub>2</sub>CH<sub>3</sub> + R′OH
 
Like the hydrolysation, transesterification is catalysed by acids and bases. The reaction is widely used for degrading [[triglyceride]]s, e.g. in the production of fatty acid esters and alcohols. [[Poly(ethylene terephthalate)]] is produced by the transesterification of [[dimethyl terephthalate]] and ethylene glycol:<ref name=Ullmann/>{{Ullmann|anno=|titolo= Esters, Organic|volume=|p=|autore= Wilhelm Riemenschneider; Hermann M. Bolt|wkautore= |doi=10.1002/14356007.a09_565.pub2}}</ref>
 
: (C<sub>6</sub>H<sub>4</sub>)(CO<sub>2</sub>CH<sub>3</sub>)<sub>2</sub> + 2&nbsp;C<sub>2</sub>H<sub>4</sub>(OH)<sub>2</sub> → {{frac|''n''}}&nbsp;{(C<sub>6</sub>H<sub>4</sub>)(CO<sub>2</sub>)<sub>2</sub>(C<sub>2</sub>H<sub>4</sub>)}<sub>''n''</sub> + 2&nbsp;CH<sub>3</sub>OH
Riga 60:
Alcoholysis of acyl chlorides and acid anhydrides
Alcohols react with [[acyl chloride]]s and [[acid anhydride]]s to give esters:
 
: RCOCl + R′OH → RCO<sub>2</sub>R′ + HCl
: (RCO)<sub>2</sub>O + R′OH → RCO<sub>2</sub>R′ + RCO<sub>2</sub>H